A conductor is a material with a high conductivity, i.e., most electrons are free to move. Perfect conductors are materials with ; this turns out to be a valid approximation for many materials (copper, silver). The opposite effect are in dielectrics.

For a finite current density and infinite conductivity , this implies:

inside a conductor, from . If we assumed , then the charges would move internally and there would be a contradiction.

Some additional ideas:

  • Perfect conductors are equipotential surfaces, i.e., , from the below equation.
    • We saw this before with copper wires (in circuits)! We say a node has the same voltage throughout, i.e., it acts as a short circuit and is equipotential!
    • And with the parallel plates of capacitors.
  • An external electric field is always perpendicular to equipotential surfaces, i.e., will enter conductors perpendicular to their surface.
    • A nice way of rationalising this is with: , which implies the dot product between and (the surface of the conductor) is 0, i.e., those vectors are perpendicular.
    • So the field lines will always hit the surface at a angle, implying the below.
  • Since field lines always originate or enter into a charge, within a conductor there can be no volume charge density.
    • From Gauss’ law, , then .
    • i.e., all free charges move to the surface.